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Lanthanide Complexes of Azidophenacyl‐DO3A as New Synthons for Click Chemistry and the Synthesis of Heterometallic Lanthanide Arrays
Author(s) -
Tropiano Manuel,
Kenwright Alan M.,
Faulkner Stephen
Publication year - 2015
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201500188
Subject(s) - lanthanide , synthon , chromophore , click chemistry , aryl , chemistry , combinatorial chemistry , triazole , luminescence , organic chemistry , materials science , ion , alkyl , optoelectronics
Lanthanide complexes of azidophenacyl DO3A are effective substrates for click reactions with ethyne derivatives, giving rise to aryl triazole appended lanthanide complexes, in which the aryl triazole acts as an effective sensitising chromophore for lanthanide luminescence. They also undergo click chemistry with propargylDO3A derivatives, giving rise to heterometallic complexes.