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Cooperative Dehydrogenation of N‐Heterocycles Using a Carbon Nanotube–Rhodium Nanohybrid
Author(s) -
Jawale Dhanaji V.,
Gravel Edmond,
Shah Nimesh,
Dauvois Vincent,
Li Haiyan,
Namboothiri Irishi N. N.,
Doris Eric
Publication year - 2015
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201500148
Subject(s) - dehydrogenation , rhodium , catalysis , carbon nanotube , nanoparticle , amine gas treating , nanotechnology , chemistry , materials science , organic chemistry , chemical engineering , engineering
Rhodium nanoparticles were anchored on carbon nanotubes and the resulting nanohybrid was studied as co‐catalyst, along with tert ‐butylcatechol, for the dehydrogenation of various N‐heterocycles. The co‐catalytic system operates in high yields, under the mildest conditions reported so far, and can be applied to a wide variety of secondary amine‐containing scaffolds.