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Back Cover: Pyranoside‐into‐Furanoside Rearrangement: New Reaction in Carbohydrate Chemistry and Its Application in Oligosaccharide Synthesis (Chem. Eur. J. 50/2014)
Author(s) -
Krylov Vadim B.,
Argunov Dmitry A.,
Vinnitskiy Dmitry Z.,
Verkhnyatskaya Stella A.,
Gerbst Alexey G.,
Ustyuzhanidezhda E.,
Dmitrenok Andrey S.,
Huebner Johannes,
Holst Otto,
Siebert HansChristian,
Nifantiev Nikolay E.
Publication year - 2014
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201490209
Subject(s) - oligosaccharide , chemistry , carbohydrate , carbohydrate chemistry , cover (algebra) , monosaccharide , polysaccharide , analogy , stereochemistry , organic chemistry , philosophy , engineering , mechanical engineering , linguistics
The new reaction in carbohydrate chemistry, namely a pyranoside‐ into ‐furanoside (PIF) rearrangement, permitting the transformation of selectively O‐substituted pyranosides into the corresponding furanosides was discovered. This process, which has no analogy in organic chemistry, was shown to be a very useful tool for the synthesis of furanoside units containing oligosaccharide derivatives related to bacterial and plant polysaccharides. For more details, see the Full Paper by N. E. Nifantiev et al. on page 16516 ff.