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Cover Picture: Development of a Ruthenium/Phosphite Catalyst System for Domino Hydroformylation–Reduction of Olefins with Carbon Dioxide (Chem. Eur. J. 23/2014)
Author(s) -
Liu Qiang,
Wu Lipeng,
Fleischer Ivana,
Selent Detlef,
Franke Robert,
Jackstell Ralf,
Beller Matthias
Publication year - 2014
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201490091
Subject(s) - hydroformylation , chemistry , catalysis , ruthenium , carbene , diphenylacetylene , combinatorial chemistry , photochemistry , organic chemistry , rhodium
Chemical activation of CO 2 is problematic due to its high thermodynamic and kinetic stability. Consequently, the use of CO 2 for the efficient construction of CC bonds represents a significant challenge. An efficient domino ruthenium‐catalyzed reverse water‐gas‐shift (RWGS)–hydroformylation–reduction reaction of olefins with CO 2 to alcohols is reported. For more details, see the Full Paper by I. Fleischer, M. Beller et al. on page 6888 ff.