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Back Cover: Integrating 31 P DOSY NMR Spectroscopy and Molecular Mechanics as a Powerful Tool for Unraveling the Chemical Structures of Polyoxomolybdate‐Based Amphiphilic Nanohybrids in Aqueous Solution (Chem. Eur. J. 18/2014)
Author(s) -
Shestakova Pavletta,
Absillis Gregory,
MartinMartinez Francisco J.,
De Proft Frank,
Willem Rudolph,
ParacVogt Tatja.
Publication year - 2014
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201490074
Subject(s) - aqueous solution , chemistry , spectroscopy , nuclear magnetic resonance spectroscopy , molecular mechanics , polyoxometalate , cover (algebra) , amphiphile , molecular dynamics , computational chemistry , organic chemistry , physics , copolymer , catalysis , mechanical engineering , polymer , quantum mechanics , engineering
It looks like magic but in the end it′s all straightforward! Linear polyoxometalate‐based hybrids have been synthesized by simply mixing (NH 4 ) 6 Mo 7 O 24 and 1,8‐octanediphosphonic acid in aqueous solution. By using a multi‐technique approach, combining 31 P DOSY, 95 Mo NMR spectroscopy and molecular mechanics calculations, the nature and length of these hybrids were determined. For more details, see the Full Paper by T. N. Parac‐Vogt et al. on p. 5258 ff.