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Cover Picture: Modulable and Highly Diastereoselective Carbometalations of Cyclopropenes (Chem. Eur. J. 4/2014)
Author(s) -
Didier Dorian,
Delaye PierreOlivier,
Simaan Marwan,
Island Biana,
Eppe Guillaume,
Eijsberg Hendrik,
Kleiner Amir,
Knochel Paul,
Marek Ilan
Publication year - 2014
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201490010
Subject(s) - stereocenter , cyclopropene , chemistry , combinatorial chemistry , cover (algebra) , stereochemistry , organic chemistry , enantioselective synthesis , catalysis , engineering , mechanical engineering
For each goal, a metal! A simple set of carbometalation‐based sequences transform readily available cyclopropene esters into a diverse variety of chiral building blocks, including quaternary stereocenters or stereodefined double bonds. Yields are high and the excellent diastereoselectivity is metal‐additive controlled. For more details see the Full Paper by I. Marek et al. on page 1038 ff.