Initial Radical Cation Pathway in the Mo 2 Cl 10 ‐Mediated Dehydrogenative Arene Coupling | Zendy

Leppin Jana | Zendy; Schubert Moritz | Zendy; Waldvogel Siegfried R. | Zendy; Heinze Katja | Zendy

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Initial Radical Cation Pathway in the Mo 2 Cl 10 ‐Mediated Dehydrogenative Arene Coupling

Author(s) -

Leppin Jana,

Schubert Moritz,

Waldvogel Siegfried R.,

Heinze Katja

Publication year - 2015

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201406522

Subject(s) - electron paramagnetic resonance , molybdenum , coupling (piping) , chemistry , electron transfer , hyperfine coupling , radical , photochemistry , crystallography , materials science , inorganic chemistry , physics , nuclear magnetic resonance , organic chemistry , metallurgy

Experimental (EPR) and theoretical (DFT) evidence is provided for radical cation formation as initial step in the Mo 2 Cl 10 ‐mediated dehydrogenative arene coupling. The initial electron transfer from methoxyarenes to molybdenum proceeds via an inner sphere mechanism.

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