Anisotropic Expansion of an M 2 L 4  Coordination Capsule: Host Capability and Frame Rearrangement | Zendy

Yamashina Masahiro | Zendy; Yuki Tsubasa | Zendy; Sei Yoshihisa | Zendy; Akita Munetaka | Zendy; Yoshizawa Michito | Zendy

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Anisotropic Expansion of an M 2 L 4 Coordination Capsule: Host Capability and Frame Rearrangement

Author(s) -

Yamashina Masahiro,

Yuki Tsubasa,

Sei Yoshihisa,

Akita Munetaka,

Yoshizawa Michito

Publication year - 2015

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201406445

Subject(s) - capsule , anisotropy , ligand (biochemistry) , elongation , fullerene , chemistry , materials science , crystallography , physics , optics , composite material , biology , organic chemistry , biochemistry , botany , receptor , ultimate tensile strength

Anisotropic expansion of a spherical M 2 L 4 coordination capsule through the elongation of the ligand led to a new M 2 L′ 4 capsule. The expanded capsule provides an elliptical cavity encircled by polyaromatic frameworks with large openings and thereby can encapsulate elliptical fullerene C 70 and monofunctionalized fullerene C 60 in high yields. In addition, selective formation of a new M 2 L 2 L′ 2 capsule occurs by mixing the original M 2 L 4 and expanded M 2 L′ 4 capsules in a 1:1 ratio upon addition of C 60 or monofunctionalized C 60 as a template molecule.

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