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Enhancing Effects of Salt Formation on Catalytic Activity and Enantioselectivity for Asymmetric Hydrogenation of Isoquinolinium Salts by Dinuclear Halide‐Bridged Iridium Complexes Bearing Chiral Diphosphine Ligands
Author(s) -
Kita Yusuke,
Yamaji Kenta,
Higashida Kosuke,
Sathaiah Kandula,
Iimuro Atuhiro,
Mashima Kazushi
Publication year - 2015
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201406234
Subject(s) - iridium , halide , asymmetric hydrogenation , salt (chemistry) , catalysis , substrate (aquarium) , chemistry , cover (algebra) , salt lake , medicinal chemistry , stereochemistry , enantioselective synthesis , organic chemistry , mechanical engineering , paleontology , oceanography , structural basin , geology , engineering , biology
Invited for the cover of this issue is the group of Kazushi Mashima at Osaka University. The image depicts a novel six‐membered outer sphere transition state—the substrate and product are represented by locomotives with a six‐membered rail, and chiral induction by a signal. Read the full text of the article at 10.1002/chem.201405408 .