An Amide‐Functionalized Dynamic Metal–Organic Framework Exhibiting Visual Colorimetric Anion Exchange and Selective Uptake of Benzene over Cyclohexane | Zendy

Karmakar Avishek | Zendy; Desai Aamod V. | Zendy; Manna Biplab | Zendy; Joarder Biplab | Zendy; Ghosh Sujit K. | Zendy

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An Amide‐Functionalized Dynamic Metal–Organic Framework Exhibiting Visual Colorimetric Anion Exchange and Selective Uptake of Benzene over Cyclohexane

Author(s) -

Karmakar Avishek,

Desai Aamod V.,

Manna Biplab,

Joarder Biplab,

Ghosh Sujit K.

Publication year - 2015

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201406233

Subject(s) - cyclohexane , thiocyanate , benzene , ligand (biochemistry) , amide , chemistry , metal ions in aqueous solution , porosity , ion exchange , copper , phase (matter) , polymer chemistry , inorganic chemistry , ion , metal , materials science , organic chemistry , biochemistry , receptor

A novel porous metal–organic framework (MOF) architecture is formed by a neutral amide‐functionalized ligand and copper(II). Upon desolvation, this compound undergoes a dynamic structural transformation from a one‐dimensional (1D) porous phase to a two‐dimensional (2D) non‐porous phase that shows selective uptake of benzene over cyclohexane. The as‐synthesized compound also acts as a visual colorimetric anion sensor for thiocyanate.

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