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Unprecedented Trinuclear Ag I Complex with 2,4,6‐Tris(2‐pyrimidyl)‐1,3,5‐triazine as an Efficient Catalyst for the Aziridination of Olefins
Author(s) -
Safin Damir A.,
Pialat Amélie,
Korobkov Ilia,
Murugesu Muralee
Publication year - 2015
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201405938
Subject(s) - catalysis , tris , denticity , triazine , chemistry , ligand (biochemistry) , polymer chemistry , medicinal chemistry , 1,3,5 triazine , combinatorial chemistry , organic chemistry , crystal structure , biochemistry , receptor
Abstract An unprecedented trinuclear heteroleptic Ag I complex was isolated using a stable multidentate 2,4,6‐tris(2‐pyrimidyl)‐1,3,5‐triazine (TPymT) ligand. The obtained compound is an efficient catalyst for the direct aziridination of terminal olefins.

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