Well‐Defined Single‐Site Monohydride Silica‐Supported Zirconium from Azazirconacyclopropane | Zendy

Hamzaoui Bilel | Zendy; Eter Mohamad El | Zendy; Abouhamad Edy | Zendy; Chen Yin | Zendy; Pelletier Jérémie D. A. | Zendy; Basset JeanMarie | Zendy

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Well‐Defined Single‐Site Monohydride Silica‐Supported Zirconium from Azazirconacyclopropane

Author(s) -

Hamzaoui Bilel,

Eter Mohamad El,

Abouhamad Edy,

Chen Yin,

Pelletier Jérémie D. A.,

Basset JeanMarie

Publication year - 2015

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201405788

Subject(s) - propene , hydrogenolysis , alkene , zirconium , ethylene , hydrogen , reactivity (psychology) , chemistry , inorganic chemistry , catalysis , organic chemistry , medicine , alternative medicine , pathology

The silica‐supported azazirconacyclopropane SiOZr(HNMe 2 )(η 2 ‐NMeCH 2 )(NMe 2 ) ( 1 ) leads exclusively under hydrogenolysis conditions (H 2 , 150 °C) to the single‐site monopodal monohydride silica‐supported zirconium species SiOZr(HNMe 2 )(NMe 2 ) 2 H ( 2 ). Reactivity studies by contacting compound 2 with ethylene, hydrogen/ethylene, propene, or hydrogen/propene, at a temperature of 200 °C revealed alkene hydrogenation.

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