New Energetic Polynitrotetrazoles | Zendy

Kettner Marcos A. | Zendy; Klapötke Thomas M. | Zendy

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New Energetic Polynitrotetrazoles

Author(s) -

Kettner Marcos A.,

Klapötke Thomas M.

Publication year - 2015

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201405659

Subject(s) - tetrazole , nitro , energetic material , fluorine , chemistry , crystal (programming language) , crystal structure , ammonium , materials science , medicinal chemistry , stereochemistry , crystallography , organic chemistry , computer science , alkyl , programming language , explosive material

This combined experimental, theoretical and comparative study details the syntheses and chemical characterisation of two new energetic polynitromethyl tetrazole derivatives, namely, 2‐(2‐nitro‐2‐azapropyl)‐5‐(trinitromethyl)‐2 H ‐tetrazole and its fluorine‐containing analogue 2‐(2‐nitro‐2‐azapropyl)‐5‐(fluorodinitromethyl)‐2 H ‐tetrazole. Their crystal structures and energetic behaviour are compared to those of their starting materials, the ammonium salts of the corresponding 5‐(polynitromethyl)‐2 H ‐tetrazoles. Additionally, the crystal structures of two further related polynitrotetrazoles are presented.

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