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Supramolecular Water Oxidation with Ru–bda‐Based Catalysts
Author(s) -
Richmond Craig J.,
Matheu Roc,
Poater Albert,
Falivene Laura,
BenetBuchholz Jordi,
Sala Xavier,
Cavallo Luigi,
Llobet Antoni
Publication year - 2014
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201405144
Subject(s) - reactivity (psychology) , catalysis , stacking , electrochemistry , catalytic cycle , supramolecular chemistry , catalytic oxidation , redox , ruthenium , chemistry , artificial photosynthesis , materials science , inorganic chemistry , chemical engineering , molecule , organic chemistry , electrode , medicine , alternative medicine , pathology , photocatalysis , engineering
Extremely slow and extremely fast new water oxidation catalysts based on the Ru–bda (bda=2,2′‐bipyridine‐6,6′‐dicarboxylate) systems are reported with turnover frequencies in the range of 1 and 900 cycles s −1 , respectively. Detailed analyses of the main factors involved in the water oxidation reaction have been carried out and are based on a combination of reactivity tests, electrochemical experiments, and DFT calculations. These analyses give a convergent interpretation that generates a solid understanding of the main factors involved in the water oxidation reaction, which in turn allows the design of catalysts with very low energy barriers in all the steps involved in the water oxidation catalytic cycle. We show that for this type of system π‐stacking interactions are the key factors that influence reactivity and by adequately controlling them we can generate exceptionally fast water oxidation catalysts.