Premium
Hydroarylations of Heterobicyclic Alkenes through Rhodium‐Catalyzed Directed CH Functionalizations of S‐Aryl Sulfoximines
Author(s) -
Dong Wanrong,
Parthasarathy Kanniyappan,
Cheng Ying,
Pan Fangfang,
Bolm Carsten
Publication year - 2014
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201404859
Subject(s) - rhodium , aryl , catalysis , chemistry , combinatorial chemistry , bicyclic molecule , organic chemistry , alkyl
Abstract Rhodium‐catalyzed directed CH‐functionalizations have been used in hydroarylations of heterobicyclic alkenes with NH‐sulfoximines. Unexpectedly, the bicyclic framework is retained, resulting in the formation of addition products being attractive intermediates for functionalized molecules that are difficult to prepare by other means.