Synergistic Catalysis: Enantioselective Addition of Alkylbenzoxazoles to Enals | Zendy

Meazza Marta | Zendy; Ceban Victor | Zendy; Pitak Mateusz B. | Zendy; Coles Simon J. | Zendy; Rios Ramon | Zendy

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Synergistic Catalysis: Enantioselective Addition of Alkylbenzoxazoles to Enals

Author(s) -

Meazza Marta,

Ceban Victor,

Pitak Mateusz B.,

Coles Simon J.,

Rios Ramon

Publication year - 2014

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201404565

Subject(s) - enantioselective synthesis , catalysis , stereoselectivity , chemistry , amine gas treating , lewis acids and bases , synergistic catalysis , combinatorial chemistry , chiral lewis acid , organic chemistry

A novel catalytic enantioselective methodology based on synergistic catalysis is reported. The strategy involves: 1) the metal‐Lewis‐acid activation of alkylazaarenes, and 2) the secondary‐amine activation of enals. Consequently, highly functionalized chiral alkylazaarenes were obtained in good yields and with reasonable stereoselectivity.

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