Palladium‐Catalysed Direct Cross‐Coupling of Organolithium Reagents with Aryl and Vinyl Triflates | Zendy

Vila Carlos | Zendy; Hornillos Valentín | Zendy; Giannerini Massimo | Zendy; FañanásMastral Martín | Zendy; Feringa Ben L. | Zendy

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Palladium‐Catalysed Direct Cross‐Coupling of Organolithium Reagents with Aryl and Vinyl Triflates

Author(s) -

Vila Carlos,

Hornillos Valentín,

Giannerini Massimo,

FañanásMastral Martín,

Feringa Ben L.

Publication year - 2014

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201404398

Subject(s) - reagent , aryl , palladium , lithium (medication) , alkyl , coupling reaction , chemistry , organolithium compounds , coupling (piping) , organic chemistry , polymer chemistry , catalysis , materials science , ion , medicine , deprotonation , metallurgy , endocrinology

A palladium‐catalysed cross‐coupling of organolithium reagents with aryl and vinyl triflates is presented. The reaction proceeds at 50 or 70 °C with short reaction times, and the corresponding products are obtained with moderate to high yields, with a variety of alkyl and (hetero)aryl lithium reagents.

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