Domino Hydroformylation/Aldol Condensation/Hydrogenation Catalysis: Highly Selective Synthesis of Ketones from Olefins | Zendy

Fang Xianjie | Zendy; Jackstell Ralf | Zendy; Börner Armin | Zendy; Beller Matthias | Zendy

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Domino Hydroformylation/Aldol Condensation/Hydrogenation Catalysis: Highly Selective Synthesis of Ketones from Olefins

Author(s) -

Fang Xianjie,

Jackstell Ralf,

Börner Armin,

Beller Matthias

Publication year - 2014

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201404294

Subject(s) - hydroformylation , regioselectivity , chemistry , aldol condensation , organic chemistry , catalysis , aldol reaction , rhodium , domino , phosphine , cascade reaction , olefin fiber

A general and highly chemo‐ and regioselective synthesis of ketones from olefins by domino hydroformylation/aldol condensation/hydrogenation reaction has been developed. A variety of olefins are efficiently converted into various ketones in good to excellent yields and regioselectivities in the presence of a specific rhodium phosphine/base–acid catalyst system.

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