The First Five‐Membered‐Heterocycle‐Fused Subphthalocyanine Analogues: Chiral Tri(benzo[ b ]thiopheno)subporphyrazines | Zendy

Shang Hong | Zendy; Zhao Luyang | Zendy; Qi Dongdong | Zendy; Chen Chao | Zendy; Jiang Jianzhuang | Zendy

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The First Five‐Membered‐Heterocycle‐Fused Subphthalocyanine Analogues: Chiral Tri(benzo[ b ]thiopheno)subporphyrazines

Author(s) -

Shang Hong,

Zhao Luyang,

Qi Dongdong,

Chen Chao,

Jiang Jianzhuang

Publication year - 2014

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201404164

Subject(s) - structural isomer , chemistry , thiophene , stereochemistry , resolution (logic) , organic chemistry , computer science , artificial intelligence

Two tri(benzo[ b ]thiopheno)subporphyrazine regioisomers with C 3 and C 1 molecular symmetry have been isolated from the cyclotrimerization of benzo[ b ]thiophene‐2,3‐dicarbonitrile as the first five‐membered‐heterocycle‐fused subphthalocyanine analogues. Optical resolution of both regioisomers was achieved by using a chiral HPLC technique, affording the first chiral subphthalocyanine analogues.

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