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( N ‐Phosphinoamidinate)cobalt‐Catalyzed Hydroboration: Alkene Isomerization Affords Terminal Selectivity
Author(s) -
Ruddy Adam J.,
Sydora Orson L.,
Small Brooke L.,
Stradiotto Mark,
Turculet Laura
Publication year - 2014
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201403945
Subject(s) - hydroboration , isomerization , alkene , cobalt , catalysis , chemistry , selectivity , boron , terminal (telecommunication) , organic chemistry , telecommunications , computer science
Abstract Herein we establish the utility of a three‐coordinate ( N ‐phosphinoamidinate)cobalt(amido) pre‐catalyst that is capable of effecting challenging alkene isomerization/hydroboration processes at room temperature, leading to the selective terminal addition of the boron group.