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The First One‐Pot Synthesis of Metal–Organic Frameworks Functionalised with Two Transition‐Metal Complexes
Author(s) -
PlateroPrats Ana E.,
Bermejo Gómez Antonio,
Samain Louise,
Zou Xiaodong,
MartínMatute Belén
Publication year - 2015
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201403909
Subject(s) - x ray absorption spectroscopy , transition metal , iridium , metal organic framework , metal , bipyridine , organic synthesis , materials science , absorption spectroscopy , rhodium , chemistry , combinatorial chemistry , absorption (acoustics) , inorganic chemistry , polymer chemistry , organic chemistry , catalysis , crystal structure , physics , composite material , adsorption , quantum mechanics
The synthesis of a metal–organic framework (UiO‐67) functionalised simultaneously with two different transition metal complexes (Ir and Pd or Rh) through a one‐pot procedure is reported for the first time. This has been achieved by an iterative modification of the synthesis parameters combined with characterisation of the resulting materials using different techniques, including X‐ray absorption spectroscopy (XAS). The method also allows the first synthesis of UiO‐67 with a very wide range of loadings (from 4 to 43 mol %) of an iridium complex ([IrCp*(bpydc)(Cl)Cl] 2− ; bpydc=2,2′‐bipyridine‐5,5′‐dicarboxylate, Cp*=pentamethylcyclopentadienyl) through a pre‐functionalisation methodology.