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New Classes of Ferromagnetic Materials with Exclusively End‐on Azido Bridges: From Single‐Molecule Magnets to 2 D Molecule‐Based Magnets
Author(s) -
Alexandropoulos Dimitris I.,
CunhaSilva Luís,
Escuer Albert,
Stamatatos Theocharis C.
Publication year - 2014
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201403815
Subject(s) - magnet , ferromagnetism , molecular magnets , molecule , materials science , polymer , metal , bridging (networking) , bridging ligand , single molecule magnet , ligand (biochemistry) , nanotechnology , crystallography , chemical physics , condensed matter physics , chemistry , magnetic field , physics , magnetization , composite material , metallurgy , organic chemistry , computer science , computer network , biochemistry , receptor , quantum mechanics
A new, flexible synthetic route, which does not require the co‐presence of any organic chelating/bridging ligand but only the “key” precursor Me 3 SiN 3 , has been discovered and led to a new class of inorganic materials containing exclusively end‐on azido bridges; the reported 3d‐metal clusters and coordination polymers exhibit ferromagnetic, single‐molecule magnet, and long‐range magnetic ordering properties.