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Large Spin‐Relaxation Barriers for the Low‐Symmetry Organolanthanide Complexes [Cp* 2 Ln(BPh 4 )] (Cp*=pentamethylcyclopentadienyl; Ln=Tb, Dy)
Author(s) -
Demir Selvan,
Zadrozny Joseph M.,
Long Jeffrey R.
Publication year - 2014
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201403751
Subject(s) - dysprosium , lanthanide , chemistry , magnetization , condensed matter physics , spin (aerodynamics) , relaxation (psychology) , dipole , terbium , single molecule magnet , crystallography , physics , magnetic field , inorganic chemistry , thermodynamics , ion , social psychology , psychology , organic chemistry , quantum mechanics
Single‐molecule magnets comprising one spin center represent a fundamental size limit for spin‐based information storage. Such an application hinges upon the realization of molecules possessing substantial barriers to spin inversion. Axially symmetric complexes of lanthanides hold the most promise for this due to their inherently high magnetic anisotropies and low tunneling probabilities. Herein, we demonstrate that strikingly large spin reversal barriers of 216 and 331 cm −1 can also be realized in low‐symmetry lanthanide tetraphenylborate complexes of the type [Cp* 2 Ln(BPh 4 )] (Cp*=pentamethylcyclopentadienyl; Ln=Tb ( 1 ) and Dy ( 2 )). The dysprosium congener showed hysteretic magnetization data up to 5.3 K. Further studies of the magnetic relaxation processes of 1 and 2 under applied dc fields and upon dilution within a matrix of [Cp* 2 Y(BPh 4 )] revealed considerable suppression of the tunneling pathway, emphasizing the strong influence of dipolar interactions on the low‐temperature magnetization dynamics in these systems.