Scalable, Transition‐Metal‐Free Direct Oxime  O ‐Arylation: Rapid Access to  O ‐Arylhydroxylamines and Substituted Benzo[ b ]furans | Zendy

Gao Hongyin | Zendy; Xu QingLong | Zendy; Keene Craig | Zendy; Kürti László | Zendy

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Scalable, Transition‐Metal‐Free Direct Oxime O ‐Arylation: Rapid Access to O ‐Arylhydroxylamines and Substituted Benzo[ b ]furans

Author(s) -

Gao Hongyin,

Xu QingLong,

Keene Craig,

Kürti László

Publication year - 2014

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201403519

Subject(s) - chemistry , oxime , transition metal , hydrolysis , sequence (biology) , sigmatropic reaction , combinatorial chemistry , stereochemistry , medicinal chemistry , organic chemistry , catalysis , biochemistry

O ‐Aryloximes, generated from readily available and inexpensive oximes through transition‐metal‐free O ‐arylation, can either be hydrolyzed to O ‐arylhydroxylamines or conveniently converted to structurally diverse benzo[ b ]furans through an environmentally benign, one‐pot [3,3]‐sigmatropic rearrangement/cyclization sequence.

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