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Two Pentasilahousanes Fused Together
Author(s) -
Tsurusaki Akihiro,
Koganezono Makoto,
Otsuka Kyohei,
Ishida Shintaro,
Kyushin Soichiro
Publication year - 2014
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201403375
Subject(s) - organosilicon , reduction (mathematics) , crystallography , cluster (spacecraft) , silicon , skeleton (computer programming) , chemistry , materials science , stereochemistry , polymer chemistry , mathematics , organic chemistry , computer science , geometry , programming language
The organosilicon cluster 1 with two pentasilahousanes fused together was synthesized by the reduction of 1,1,3‐trichlorocyclotetrasilane. This reaction involves dimerization and rearrangement of the silicon skeleton. The structure and properties of 1 were studied by X‐ray crystallographic and spectroscopic analyses.