The Metallofullerene Field‐Induced Single‐Ion Magnet HoSc 2 N@C 80 | Zendy

Dreiser Jan | Zendy; Westerström Rasmus | Zendy; Zhang Yang | Zendy; Popov Alexey A. | Zendy; Dunsch Lothar | Zendy; Krämer Karl | Zendy; Liu ShiXia | Zendy; Decurtins Silvio | Zendy; Greber Thomas | Zendy

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The Metallofullerene Field‐Induced Single‐Ion Magnet HoSc 2 N@C 80

Author(s) -

Dreiser Jan,

Westerström Rasmus,

Zhang Yang,

Popov Alexey A.,

Dunsch Lothar,

Krämer Karl,

Liu ShiXia,

Decurtins Silvio,

Greber Thomas

Publication year - 2014

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201403042

Subject(s) - metallofullerene , ion , field (mathematics) , magnet , materials science , physics , atomic physics , condensed matter physics , nuclear magnetic resonance , mathematics , metal , metallurgy , quantum mechanics , pure mathematics

The low‐temperature magnetic properties of the endohedral metallofullerene HoSc 2 N@C 80 have been studied by superconducting quantum interference device (SQUID) magnetometry. Alternating current (ac) susceptibility measurements reveal that this molecule exhibits slow relaxation of magnetization in a small applied field with timescales in the order of milliseconds. The equilibrium magnetic properties of HoSc 2 N@C 80 indicate strong magnetic anisotropy. The large differences in magnetization relaxation times between the present compound and the previously investigated DySc 2 N@C 80 are discussed.

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