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Novel Method for the Fabrication of a Charge‐Transfer Complex Crystal by Photoirradiation
Author(s) -
Matsuda Masaki,
Nishi Miki,
Koga Shoko,
Fujishima Mika,
Hoshino Norihisa,
Akutagawa Tomoyuki,
Hasegawa Hiroyuki
Publication year - 2014
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201402644
Subject(s) - charge transfer complex , crystal (programming language) , fabrication , phthalocyanine , charge (physics) , homo/lumo , crystal structure , materials science , chemistry , electron transfer , photochemistry , crystallography , molecule , nanotechnology , organic chemistry , physics , computer science , medicine , alternative medicine , pathology , quantum mechanics , programming language
A novel method for the fabrication of a charge‐transfer complex crystal was developed. Photoirradiation of a solution of TPP[Co(tbp)(CN) 2 ] and TPP[Co(Pc)(CN) 2 ] (tbp=tetrabenzoporphyrin, Pc=phthalocyanine, TPP=tetraphenylphosphonium) gave a molecular conducting crystal of a charge‐transfer complex TPP[Co(tbp)(CN) 2 ] 2 , which was produced by the process in which the photoexcited electron in tbp was transferred from the LUMO of tbp to that of Pc.