Rhodium‐Catalyzed Intramolecular [3+2+2] Cycloadditions between Alkylidenecyclopropanes, Alkynes, and Alkenes | Zendy

Araya Marisel | Zendy; Gulías Moisés | Zendy; Fernández Israel | Zendy; Bhargava Gaurav | Zendy; Castedo Luis | Zendy; Mascareñas José Luis | Zendy; López Fernando | Zendy

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Rhodium‐Catalyzed Intramolecular [3+2+2] Cycloadditions between Alkylidenecyclopropanes, Alkynes, and Alkenes

Author(s) -

Araya Marisel,

Gulías Moisés,

Fernández Israel,

Bhargava Gaurav,

Castedo Luis,

Mascareñas José Luis,

López Fernando

Publication year - 2014

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201402473

Subject(s) - cycloaddition , intramolecular force , chemoselectivity , rhodium , catalysis , chemistry , intramolecular reaction , combinatorial chemistry , medicinal chemistry , stereochemistry , organic chemistry

A Rh‐catalyzed intramolecular [3+2+2] cycloaddition is reported. The cycloaddition affords synthetically relevant 5,7,5‐fused tricyclic systems of type 2 from readily available dienyne precursors. The transformation takes place with moderate or good yields, high diastereoselectivity, and total chemoselectivity.

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