Ruthenium(II)‐Catalyzed Synthesis of Isochromenes by CH Activation with Weakly Coordinating Aliphatic Hydroxyl Groups | Zendy

Nakanowatari Sachiyo | Zendy; Ackermann Lutz | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Ruthenium(II)‐Catalyzed Synthesis of Isochromenes by CH Activation with Weakly Coordinating Aliphatic Hydroxyl Groups

Author(s) -

Nakanowatari Sachiyo,

Ackermann Lutz

Publication year - 2014

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201400161

Subject(s) - annulation , cationic polymerization , ruthenium , chemistry , metalation , catalysis , surface modification , medicinal chemistry , combinatorial chemistry , polymer chemistry , organic chemistry

Cationic ruthenium(II) complexes have been employed for the highly effective oxidative annulation of alkynes with benzyl alcohols to deliver diversely decorated isochromenes. The hydroxyl‐directed CH/OH functionalization process proceeded efficiently under an atmosphere of air. Detailed mechanistic studies were indicative of a kinetically relevant CH metalation.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research