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NIS‐Assisted Aza‐Friedel–Crafts Reaction with α‐Carbamoysulfides as Precursors of N ‐Carbamoylimines
Author(s) -
George Nicolas,
Bekkaye Mathieu,
Alix Aurélien,
Zhu Jieping,
Masson Géraldine
Publication year - 2014
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201400117
Subject(s) - friedel–crafts reaction , nucleophile , chemistry , combinatorial chemistry , reaction conditions , organic chemistry , medicinal chemistry , catalysis
A general and practical N ‐iodosuccinimide (NIS)‐promoted aza‐Friedel–Crafts reaction of various aromatic nucleophiles with N ‐acylimines generated in situ from α‐amidosulfides to give a rapid access to highly functionalized amines is described. The newly developed methodology is very mild, fast, efficient, and complementary.

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