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Palladium/Norbornene‐Mediated Tandem CH Amination/CI Alkenylation Reaction of Aryl Iodides with Secondary Cyclic O ‐Benzoyl Hydroxylamines and Activated Terminal Olefins
Author(s) -
Chen ZhiYuan,
Ye ChangQing,
Zhu Hui,
Zeng XingPing,
Yuan JianJun
Publication year - 2014
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201400084
Subject(s) - norbornene , palladium , chemistry , amination , tandem , aryl , catalysis , medicinal chemistry , organic chemistry , combinatorial chemistry , materials science , polymer , alkyl , composite material , monomer
A novel palladium‐catalyzed norbornene‐mediated three‐component reaction for the construction of ortho ‐alkenyl aromatic tertiary amines has been achieved, which represents a useful extension of the Catellani‐type tandem ortho ‐selective CH amination transformations.