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Direct Olefination of Fluorinated Benzothiadiazoles: A New Entry to Optoelectronic Materials
Author(s) -
Xiao YuLan,
Zhang Bo,
He ChunYang,
Zhang Xingang
Publication year - 2014
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201400075
Subject(s) - olefin fiber , compatibility (geochemistry) , palladium , materials science , catalysis , reaction conditions , chemical engineering , combinatorial chemistry , optoelectronics , chemistry , organic chemistry , composite material , engineering
Fluorinated olefin‐containing benzothiadiazoles have important applications in optoelectronic materials. Herein, we reported the direct olefination of fluorinated benzothiadiazoles, as catalyzed by palladium. The reaction proceeds under mild reaction conditions and shows high functional‐group compatibility. A preliminary study of the properties of the resulting symmetrical and unsymmetrical olefin‐containing fluorinated benzothiadiazoles in red‐light‐emitting dyes has also been conducted.