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Back Cover: Synthesis, Structure, and Reactivity of Lewis Base Stabilized Plumbacyclopentadienylidenes (Chem. Eur. J. 50/2013)
Author(s) -
Saito Masaichi,
Akiba Tomoki,
Kaneko Misumi,
Kawamura Toshiaki,
Abe Minori,
Hada Masahiko,
Minoura Mao
Publication year - 2013
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201390201
Subject(s) - adduct , lewis acids and bases , reactivity (psychology) , frustrated lewis pair , cover (algebra) , chemistry , atom (system on chip) , polymer chemistry , organic chemistry , catalysis , computer science , medicine , mechanical engineering , alternative medicine , pathology , engineering , embedded system
Plumbacyclopentadienylidenes in which the lead atom is coordinated to a variety of Lewis bases, including THF, exhibit interesting behavior and reactivity. In their Full Paper on page 16946 ff. , M. Saito et al. show that the THF adduct, which is a rare example of a 10‐X‐4 species, reacts with trifluoroborane or trichlorogallane to afford fluoroborole and chlorogallole, respectively.