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Two‐Dimensional Assembly Based on Flow Supramolecular Chemistry: Kinetic Control of Molecular Interactions Under Solvent Diffusion
Author(s) -
Numata Munenori,
Kozawa Tomohiro
Publication year - 2014
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201305006
Subject(s) - supramolecular chemistry , porphyrin , solvent , diffusion , chemistry , micrometer , molecular diffusion , supramolecular assembly , molecule , nanotechnology , kinetic control , chemical physics , self assembly , materials science , organic chemistry , thermodynamics , catalysis , physics , metric (unit) , operations management , optics , economics
Self‐assembly of porphyrin molecules can be controlled kinetically to form structures with lengths extending from the nano‐ to the micrometer scale, through a programmed solvent‐diffusion process in designed microflow spaces. Temporal solvent structures generated in the microflow were successfully transcribed into molecular architectures.