Carbene‐9‐BBN Ring Expansions as a Route to Intramolecular Frustrated Lewis Pairs for CO 2  Reduction | Zendy

Wang Tongen | Zendy; Stephan Douglas W. | Zendy

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Carbene‐9‐BBN Ring Expansions as a Route to Intramolecular Frustrated Lewis Pairs for CO 2 Reduction

Author(s) -

Wang Tongen,

Stephan Douglas W.

Publication year - 2014

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201304870

Subject(s) - frustrated lewis pair , boranes , intramolecular force , ring (chemistry) , phosphine , borane , chemistry , nonane , carbene , lewis acids and bases , reduction (mathematics) , medicinal chemistry , catalysis , boron , stereochemistry , organic chemistry , mathematics , geometry

Reactions of phosphine‐derived carbenes with 9‐borabicyclo[3.3.1]nonane (9‐BBN) result in ring‐expansion reactions to generate novel intramolecular frustrated Lewis pairs (FLPs). These FLPs effect the catalytic reduction of CO 2 in the presence of boranes to give BOB and methoxy‐borate species.

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