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Hetero‐Epitaxial Approach by Using Labile Coordination Sites to Prepare Catenated Metal–Organic Frameworks with High Surface Areas
Author(s) -
Zhu Nianyong,
Lennox Matthew J.,
Tobin Gerard,
Goodman Lisa,
Düren Tina,
Schmitt Wolfgang
Publication year - 2014
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201304856
Subject(s) - metal organic framework , acetylene , blueprint , epitaxy , materials science , phase (matter) , nanotechnology , chemistry , topology (electrical circuits) , organic chemistry , adsorption , layer (electronics) , engineering , mechanical engineering , electrical engineering
A solid‐state approach that takes advantage of the ordered 3D arrangement of active secondary building units allows the preparation of new interlocked MOFs that grow hetero‐epitaxially on the crystal faces of a precursor phase that acts as a “topological blueprint”. The synthetic strategy is exemplified by using rigid acetylene‐based ligands to produce highly augmented Cu II acetate‐based MOFs.