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Combining Complementary Ligands into one Framework for the Construction of a Ferromagnetically Coupled [Mn III 12 ] Wheel
Author(s) -
Sanz Sergio,
Frost Jamie M.,
Rajeshkumar Thayalan,
Dalgarno Scott J.,
Rajaraman Gopalan,
Wernsdorfer Wolfgang,
Schnack Jürgen,
Lusby Paul. J.,
Brechin Euan K.
Publication year - 2014
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201304740
Subject(s) - diethanolamine , oxime , ligand (biochemistry) , construct (python library) , chemistry , type (biology) , crystallography , stereochemistry , materials science , computer science , organic chemistry , programming language , ecology , biology , biochemistry , receptor
Abstract Phenolic oxime and diethanolamine moieties have been combined into one organic framework, resulting in the formation of a novel ligand type that can be employed to construct a rare and unusual dodecametallic Mn wheel, within which nearest neighbours are coupled ferromagnetically.