Premium
Rhodium‐Catalyzed [2+2+2] Cycloaddition of Diynes with Carbodiimides and Carbon Dioxide under Ambient Conditions
Author(s) -
Ishii Masahiro,
Mori Fumiya,
Tanaka Ken
Publication year - 2014
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201304623
Subject(s) - rhodium , cycloaddition , carbon dioxide , catalysis , chemistry , organic chemistry
It has been established that a cationic rhodium(I)/H 8 ‐binap complex is able to catalyze the [2+2+2] cycloaddition of diynes with carbodiimides and carbon dioxide under ambient conditions. Enantio‐ and/or regioselective variants of these reactions are also disclosed.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom