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Exploring the Synthesis of a New Group of Chiral Ammonium Salts with Specific Configurations at the Stereogenic Nitrogen Centers
Author(s) -
Eckert Prisca K.,
Golz Christopher,
Degen Patrick,
Werner Cornelia,
Rehage Heinz,
Strohmann Carsten
Publication year - 2014
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201304433
Subject(s) - stereocenter , stereoselectivity , recrystallization (geology) , nitrogen , ammonium , group (periodic table) , amphiphile , chemistry , stereochemistry , enantioselective synthesis , organic chemistry , catalysis , biology , copolymer , paleontology , polymer
A group of new chiral dications with a fixed, specific configuration at the stereogenic nitrogen center was created. Stereoselective synthesis and recrystallization give the diastereomerically and enantiomerically pure dications, including a chiral amphiphile with surface‐active properties.