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Highly Luminescent N‐Doped Carbon Quantum Dots as an Effective Multifunctional Fluorescence Sensing Platform
Author(s) -
Qian Zhaosheng,
Ma Juanjuan,
Shan Xiaoyue,
Feng Hui,
Shao Linxiang,
Chen Jianrong
Publication year - 2014
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201304374
Subject(s) - fluorescence , quantum dot , quantum yield , quenching (fluorescence) , protonation , carbon fibers , aqueous solution , carbon quantum dots , materials science , luminescence , photochemistry , nitrogen , nanotechnology , analytical chemistry (journal) , chemistry , organic chemistry , optoelectronics , ion , physics , composite number , composite material , quantum mechanics
The doping of carbon quantum dots with nitrogen provides a promising direction to improve fluorescence performance and broaden their applications in sensing systems. Herein we report a one‐pot solvothermal synthesis of N‐doped carbon quantum dots (NCQDs) and the synthesis of a series of NCQDs with different nitrogen contents. The as‐prepared NCQDs were compared with carbon quantum dots (CQDs); the introduction of nitrogen atoms largely increased the quantum yield of NCQDs and highest emission efficiency is up to 36.3 %. The fluorescence enhancement may originate from more polyaromatic structures induced by incorporated nitrogen atoms and protonation of nitrogen atoms on dots. It was found that NCQDs can act as a multifunctional fluorescence sensing platform because they can be used to detect pH values, Ag I , and Fe III in aqueous solution. The fluorescence intensity of NCQDs is inversely proportional to pH values across a broad range from 5.0 to 13.5, which indicates that NCQDs can be devised as an effective pH indicator. Selective detection of Ag I and Fe III was achieved based on their distinctive fluorescence influence because Ag I can significantly enhance the fluorescence whereas Fe III can greatly quench the fluorescence. The quantitative determination of Ag I can be accomplished with NCQDs by using the linear relationship between fluorescence intensity of NCQDs and concentration of Ag I . The sensitive detection of H 2 O 2 was developed by taking advantage of the distinct quenching ability of Fe III and Fe II toward the fluorescence of NCQDs. Cellular toxicity test showed NCQDs still retain low toxicity to cells despite the introduction of a great deal of nitrogen atoms. Moreover, bioimaging experiments demonstrated that NCQDs have stronger resistance to photobleaching than CQDs and more excellent fluorescence labeling performance.