Silver‐Catalyzed Cross‐Coupling of Propargylic Alcohols with Isocyanides: An Atom‐Economical Synthesis of 2,3‐Allenamides | Zendy

Liu Jianquan | Zendy; Liu Zhenhua | Zendy; Wu Nannan | Zendy; Liao Peiqiu | Zendy; Bi Xihe | Zendy

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Silver‐Catalyzed Cross‐Coupling of Propargylic Alcohols with Isocyanides: An Atom‐Economical Synthesis of 2,3‐Allenamides

Author(s) -

Liu Jianquan,

Liu Zhenhua,

Wu Nannan,

Liao Peiqiu,

Bi Xihe

Publication year - 2014

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201304255

Subject(s) - catalysis , coupling (piping) , atom (system on chip) , chemistry , combinatorial chemistry , organic chemistry , materials science , computer science , parallel computing , metallurgy

Cross‐coupling reactions between propargylic alcohols and isocyanides, by means of silver catalysis, have been described. This new reaction is both atom and step efficient and is applicable to a broad scope of substrates, allowing the synthesis of a range of synthetically valuable 2,3‐allenamides in moderate to excellent yields.

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