Premium
A Direct, Modular, and Efficient Construction of the PCP Structural Motif through Coupling of Manganese Carbyne Complexes with Phosphines
Author(s) -
Valyaev Dmitry A.,
Bastin Stéphanie,
Utegenov Kamil I.,
Lugan Noël,
Lavigne Guy,
Ustynyuk Nikolai A.
Publication year - 2014
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201304239
Subject(s) - carbyne , manganese , chemistry , modular design , coupling (piping) , stereochemistry , crystallography , materials science , organic chemistry , metallurgy , catalysis , computer science , carbene , operating system
Easily available carbyne complexes of manganese were used as a source of carbyne fragments in an unconventional synthesis of backbone‐substituted diphosphinomethanes and cyclic P‐ylides upon coupling with secondary or tertiary phosphines, respectively, followed by demetalation under mild conditions.