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Reversible Light‐Driven Polymerization of Polyoxometalate Tethered with Coumarin Molecules
Author(s) -
Tong UnSong,
Chen Wei,
Ritchie Chris,
Wang Xiaoting,
Song YuFei
Publication year - 2014
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201303933
Subject(s) - polyoxometalate , coumarin , polymerization , covalent bond , chemistry , molecule , polymer chemistry , fourier transform infrared spectroscopy , photochemistry , cluster (spacecraft) , polymer , nuclear magnetic resonance spectroscopy , organic chemistry , chemical engineering , catalysis , computer science , engineering , programming language
A new photosensitive polyoxometalate (POM) organic–inorganic hybrid compound has been prepared by covalently tethering coumarin moieties onto a Mn–Anderson cluster. This compound has been fully characterized by 1 H NMR, 13 C NMR, FTIR, and UV/Vis spectroscopy, and ESI‐MS. This organic–inorganic hybrid compound can undergo reversible light‐driven polymerization and this process has been characterized in detail.