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Isolatable Organophosphorus(III)–Tellurium Heterocycles
Author(s) -
Nordheider Andreas,
Chivers Tristram,
Schön Oliver,
Karaghiosoff Konstantin,
Athukorala Arachchige Kasun S.,
Slawin Alexandra M. Z.,
Woollins J. Derek
Publication year - 2014
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201303884
Subject(s) - tellurium , ferrocene , chemistry , crystal structure , stereochemistry , crystallography , medicinal chemistry , organic chemistry , electrochemistry , electrode
A new structural arrangement Te 3 (RP III ) 3 and the first crystal structures of organophosphorus(III)–tellurium heterocycles are presented. The heterocycles can be stabilized and structurally characterized by the appropriate choice of substituents in Te m (P III R) n ( m =1: n =2, R=OMes* (Mes*=supermesityl or 2,4,6‐tri‐ tert ‐butylphenyl); n =3, R=adamantyl (Ad); n =4, R=ferrocene (Fc); m = n =3: R=trityl (Trt), Mesor by the installation of a P V 2 N 2 anchor in RP III [TeP V ( t BuN)(μ‐N t Bu)] 2 (R=Ad, t Bu).