Isolatable Organophosphorus(III)–Tellurium Heterocycles | Zendy

Nordheider Andreas | Zendy; Chivers Tristram | Zendy; Schön Oliver | Zendy; Karaghiosoff Konstantin | Zendy; Athukorala Arachchige Kasun S. | Zendy; Slawin Alexandra M. Z. | Zendy; Woollins J. Derek | Zendy

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Isolatable Organophosphorus(III)–Tellurium Heterocycles

Author(s) -

Nordheider Andreas,

Chivers Tristram,

Schön Oliver,

Karaghiosoff Konstantin,

Athukorala Arachchige Kasun S.,

Slawin Alexandra M. Z.,

Woollins J. Derek

Publication year - 2014

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201303884

Subject(s) - tellurium , ferrocene , chemistry , crystal structure , stereochemistry , crystallography , medicinal chemistry , organic chemistry , electrochemistry , electrode

A new structural arrangement Te 3 (RP III ) 3 and the first crystal structures of organophosphorus(III)–tellurium heterocycles are presented. The heterocycles can be stabilized and structurally characterized by the appropriate choice of substituents in Te m (P III R) n ( m =1: n =2, R=OMes* (Mes*=supermesityl or 2,4,6‐tri‐ tert ‐butylphenyl); n =3, R=adamantyl (Ad); n =4, R=ferrocene (Fc); m = n =3: R=trityl (Trt), Mesor by the installation of a P V 2 N 2 anchor in RP III [TeP V ( t BuN)(μ‐N t Bu)] 2 (R=Ad, t Bu).

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