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Alkylation of Terminal Alkynes with Transient σ‐Alkylpalladium(II) Complexes: A Carboalkynylation Route to Alkyl‐Substituted Alkynes
Author(s) -
Zhou MingBo,
Huang XiaoCheng,
Liu YanYun,
Song RenJie,
Li JinHeng
Publication year - 2014
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201303879
Subject(s) - alkylation , alkyl , transient (computer programming) , terminal (telecommunication) , chemistry , medicinal chemistry , organic chemistry , catalysis , computer science , telecommunications , operating system
A mild and general alkylation of terminal alkynes with transient σ‐alkylpalladium(II) complexes for assembling alkyl‐substituted alkynes is described. This method represents a new way to the use of transient σ‐alkylpalladium(II) complexes in organic synthesis through 1,2‐carboalkynylation of alkenes.