Tailor‐Made Hybrid Organic–Inorganic Porous Materials Based on Polyhedral Oligomeric Silsesquioxanes (POSS) by the Step‐Growth Mechanism of Thiol‐Ene “Click” Chemistry | Zendy

Alves Filipa | Zendy; Nischang Ivo | Zendy

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Tailor‐Made Hybrid Organic–Inorganic Porous Materials Based on Polyhedral Oligomeric Silsesquioxanes (POSS) by the Step‐Growth Mechanism of Thiol‐Ene “Click” Chemistry

Author(s) -

Alves Filipa,

Nischang Ivo

Publication year - 2013

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201303759

Subject(s) - silsesquioxane , click chemistry , ene reaction , thiol , porosity , materials science , polymer chemistry , chemical engineering , porous medium , oligomer , chemistry , polymer science , polymer , organic chemistry , composite material , engineering

Clicking 3D materials : Hybrid, organic–inorganic polyhedral oligomeric silsesquioxane precursors are woven into macroscopically shaped entities by thiol‐ene chemistry in a radical‐mediated, step‐growth fashion, by photo or thermal initiation (see figure). The materials are nanostructured and their macroporous features and physical properties are easily tailored.

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