Disproportionation of Achiral Nickel(II) Centers into Two Kinds of Chiral Nickel(II) Centers Caused by an Achiral Diimine Ligand | Zendy

IgashiraKamiyama Asako | Zendy; Fukushima Akeha | Zendy; Konno Takumi | Zendy

Premium

Disproportionation of Achiral Nickel(II) Centers into Two Kinds of Chiral Nickel(II) Centers Caused by an Achiral Diimine Ligand

Author(s) -

IgashiraKamiyama Asako,

Fukushima Akeha,

Konno Takumi

Publication year - 2013

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201303731

Subject(s) - diimine , disproportionation , nickel , ligand (biochemistry) , octahedron , crystallography , chemistry , coordination complex , materials science , crystal structure , catalysis , organic chemistry , biochemistry , receptor , metal

Chiral creation : A disproportionation reaction, in which achiral square‐planar Ni II centers are converted into two kinds of chiral, octahedral Ni II centers on treatment with an achiral diimine ligand, was discovered in a D ‐penicillaminato Au I Ni II coordination system, presenting a unique method for generating and increasing chiral centers (see scheme).

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research