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Disproportionation of Achiral Nickel(II) Centers into Two Kinds of Chiral Nickel(II) Centers Caused by an Achiral Diimine Ligand
Author(s) -
IgashiraKamiyama Asako,
Fukushima Akeha,
Konno Takumi
Publication year - 2013
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201303731
Subject(s) - diimine , disproportionation , nickel , ligand (biochemistry) , octahedron , crystallography , chemistry , coordination complex , materials science , crystal structure , catalysis , organic chemistry , biochemistry , receptor , metal
Chiral creation : A disproportionation reaction, in which achiral square‐planar Ni II centers are converted into two kinds of chiral, octahedral Ni II centers on treatment with an achiral diimine ligand, was discovered in a D ‐penicillaminato Au I Ni II coordination system, presenting a unique method for generating and increasing chiral centers (see scheme).