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Probing the Effects of Ligand Isomerism in Chiral Luminescent Lanthanide Supramolecular Self‐Assemblies: A Europium “Trinity Sliotar” Study
Author(s) -
Kotova Oxana,
Kitchen Jonathan A.,
Lincheneau Christophe,
Peacock Robert D.,
Gunnlaugsson Thorfinnur
Publication year - 2013
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201303660
Subject(s) - lanthanide , europium , luminescence , chirality (physics) , supramolecular chemistry , ligand (biochemistry) , chemistry , stereochemistry , naphthalene , crystallography , materials science , photochemistry , combinatorial chemistry , crystal structure , organic chemistry , receptor , optoelectronics , ion , biochemistry , chiral symmetry breaking , physics , quantum mechanics , nambu–jona lasinio model , quark
“Trinity Sliotar” family : Chiral ligands containing pyridyl and naphthalene moieties were synthesized and characterized. These ligands were successfully used for the synthesis of Eu III bundles where chirality of the ligand is successfully transferred onto the lanthanide centre resulting in circularly polarized red luminescence.