Crystallographic Characterization of a Fully Rotated, Basic Diiron Dithiolate: Model for the H red  State? | Zendy

Wang Wenguang | Zendy; Rauchfuss Thomas B. | Zendy; Moore Curtis E. | Zendy; Rheingold Arnold L. | Zendy; De Gioia Luca | Zendy; Zampella Giuseppe | Zendy

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Crystallographic Characterization of a Fully Rotated, Basic Diiron Dithiolate: Model for the H red State?

Author(s) -

Wang Wenguang,

Rauchfuss Thomas B.,

Moore Curtis E.,

Rheingold Arnold L.,

De Gioia Luca,

Zampella Giuseppe

Publication year - 2013

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201303351

Subject(s) - state (computer science) , computer science , characterization (materials science) , service (business) , information retrieval , steric effects , crystallography , chemistry , algorithm , nanotechnology , stereochemistry , materials science , business , marketing

A lucky break : A combination of steric pressure and electron asymmetry has provided the first example of a diiron dithiolate that is both rotated and basic. The present work establishes the feasibility of a hydride free rotated structure for the H red state of the enzyme (see figure).

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