A Copper(I)‐Catalyzed Three‐Component Domino Process: Assembly of Complex 1,2,3‐Triazolyl‐5‐Phosphonates from Azides, Alkynes, and  H ‐Phosphates | Zendy

Li Lingjun | Zendy; Hao Guoliang | Zendy; Zhu Anlian | Zendy; Fan Xincui | Zendy; Zhang Guisheng | Zendy; Zhang Lihe | Zendy

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A Copper(I)‐Catalyzed Three‐Component Domino Process: Assembly of Complex 1,2,3‐Triazolyl‐5‐Phosphonates from Azides, Alkynes, and H ‐Phosphates

Author(s) -

Li Lingjun,

Hao Guoliang,

Zhu Anlian,

Fan Xincui,

Zhang Guisheng,

Zhang Lihe

Publication year - 2013

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201303324

Subject(s) - alkyne , phosphonate , domino , catalysis , azide , chemistry , copper , combinatorial chemistry , click chemistry , phosphate , component (thermodynamics) , cascade reaction , organic chemistry , polymer chemistry , physics , thermodynamics

Three is better than one! A new copper‐catalyzed tricomponent reaction of a terminal alkyne, organic azide, and H ‐phosphate (CuAA[P]C) leads to a structurally diverse polysubstituted 1,2,3‐triazolyl‐5‐phosphonate, which provides an efficient tool for the direct introduction of phosphonic acid groups by a “click reaction” (see scheme).

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